Sample Code:

<apex:page showHeader=”false” controller=”Sample” >
<apex:form >
    <apex:panelGrid columns=”1″ style=”float:right;”>
        <apex:commandButton value=”One”/>
        <apex:commandButton value=”Two”/>
        <apex:commandButton value=”Three”/>
        <apex:commandButton value=”Four”/>
        <apex:commandButton value=”Five”/>
    </apex:panelGrid>
</apex:form>    
</apex:page>

Output: